Condensation of crotonic and tiglic acid dianions with.
IUPAC Standard InChIKey: UIERETOOQGIECD-ONEGZZNKSA-N CAS Registry Number: 80-59-1 Chemical structure: This structure is also available as a 2d Mol file; Species with the same structure: (E)-2-Methyl-2-butenoic acid.
Together with tiglic acid form a pair of cis-trans isomers. Angelic acid is a volatile body, of biting acid taste and pungent sour odour. It crystallizes in colorless monoclinic prisms. Angelic acid was formerly used therapeutically as a sedative.; Angelic acid is a monocarboxylic unsaturated organic acid.
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The Siegel Synthesis of Eupalinilide E.. Esterification of 2 with tiglic acid (11) by the Yamaguchi procedure then led to 12. The ester 12 was readily desilylated on exposure to trifluoroacetic acid. The challenge was the selective oxidation of the desilylated intermediate to the keto lactone 13.
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Tiglic acid is a monocarboxylic unsaturated organic acid found in croton oil and in several other natural products. It is used in making perfumes and flavoring agents.. Puromycin 2HCl is an aminonucleoside antibiotic, which acts as a protein synthesis inhibitor. Cyclosporin A Cyclosporin A is an immunosuppressive agent.